Electronic structures and magnetic properties of Zn-and Cd-doped AlN nanosheets:A first-principles study

In this paper, the magnetic properties, electronic structures and the stabilities of Zn/Cd incorporated two-dimensional Al N nanosheets are investigated by the first-principles method. Numerical results indicate that Zn and Cd substituting Al atom in Al N nanosheets introduce some holes into the 2p orbitals of the N atoms, and the holes mainly come from spindown 2p orbitals of the N atoms. The magnetic moment of 1.0 μBis produced by Zn/Cd doping Al N nanosheets, and the main component of the magnetic moment of the system is contributed by the partially filled 2p states of the N atoms around the dopant. In particular, when Zn/Cd substituting Al atoms, the magnetic coupling is found to be ferromagnetic. We attribute the hole-mediated p–d interaction to the created ferromagnetic coupling. More importantly, the result of formation energy indicates that Al atom is more inclined to be replaced by Zn atom rather than Cd. This finding is beneficial to developing the spin electronic devices.     

Spatiotemporal evolution of continuous-wave field and dark soliton formation in a microcavity with normal dispersion

Stable dark soliton and dark pulse formation in normally dispersive and red-detuned microcavities are investigated by numerically solving the normalized Lugiato-Lefever equation. The soliton essence is proved by fitting the calculated field intensity profile with the analytical formula of a dark soliton. Meanwhile, we find that a dark soliton can be generated either from the nonlinear evolution of an optical shock wave or narrowing of a locally broad dark pulse with smoother fronts. Explicit analytical expression is obtained to describe the oscillatory fronts of the optical shock wave. Furthermore,from the calculation results, we show that for smaller frequency detunings, e.g., α 3, in addition to the dark soliton formation, a single dark pulse with an oscillatory dip can also arise and propagate stably in the microcavity under proper pump detuning and pump strength combination. The existence region together with various field intensity profiles and the corresponding spectra of single dark pulse are demonstrated.     

Effects of pressure on structural,electronic, and mechanical properties of α,β,and γ uranium

The first-principles methods have been employed to calculate the structural, electronic, and mechanical properties of the α, β, and γ phases of uranium under pressure up to 100 GPa. The electronic structure has been viewed in forms of density of states and band structure. The mechanical stability of metal U in the α, β, and γ phases have been examined.The independent elastic constants, polycrystalline elastic moduli, as well as Poisson's ratio have been obtained. Upon compression, the elastic constants, elastic moduli, elastic wave velocities, and Debye temperature of α phase are enhanced pronouncedly. The value of B/G illustrates that α and γ phases are brittle in ground state.     

Velocity-selective spectroscopy measurements of Rydberg fine structure states in a hot vapor cell

A velocity-selective spectroscopy technique for studying the spectra of Rydberg gases is presented. This method provides high-resolution spectrum measurements. We present experimental results for a ladder system 6S_(1/2)→ 6P_(3/2)→ nS(D)electromagnetically-induced transparency involving highly-excited Rydberg states. Based on a radio-frequency modulation technique, we measure the hyperfine structure splitting of intermediate states and the fine structure splitting of Rydberg states in a room temperature ~(133)Cs vapor cell. The experimental data and theoretical predictions show excellent agreement.     

基于量子相干效应的无芯射频识别标签的空间散射场测量

基于原子蒸汽池中铯里德伯原子的电磁感应透明光谱在微波场作用下的Aulter-Towns效应,测量了无芯射频识别标签线形散射单元的近场散射微波电场二维空间分布,空间分辨率可达到亚微波波长.实现了射频电场极化方向与线形散射体标签夹角的有效分辨.电磁仿真软件的仿真结果与实验测量符合得很好.本研究提供了一种测量微波电场近场测量的新方法,对无芯射频识别标签的散射单元设计和标定以及电子电路的电磁辐射测量具有重要的意义.     

基于多特征差异检测与联合控制映射的红外图像选择加密算法

为了实现对红外图像的选择性加密,提出了基于多特征差异检测与联合控制映射的红外图像选择算法。引入分段正弦变换,将输出图像分割为3个不同的区域,对每个区域完成不同的拉伸变换,完成初始红外图像的增强,凸显真实红外目标;再利用增强图像中目标与背景的灰度差异,从而设计目标决策因子,并分割Top-Hat变换的结构元素,构建红外背景抑制机制,过滤杂波与噪声;利用灰度水平、对比度与相似度,建立多特征差异检测模型,提取包含真实目标与可疑目标的感兴趣区域;以Logistic映射为控制条件,综合Tent映射与Chebyshev映射,设计联合控制混沌映射,利用其输出的混合随机序列对感兴趣区域进行置乱;引入引力模型,对混淆的感兴趣区域内的像素进行扩散,完成红外目标选择加密。实验结果显示:与已有的图像局部加密机制相比,该文算法输出密文信息熵值达到了7.982 6,能够更好地用于红外图像局部选择性加密。     

共轭聚合物单分子构象和能量转移特性研究

利用基于宽场显微光学系统的单分子散焦成像技术测量了不同构象poly[2,7-(9,9-dioctylfluorene)-alt-4,7-bis(thiophen-2-yl)benzo-2,1,3-thiadiazole](PFO-DBT)共轭聚合物单分子的光物理与动力学特性.通过分析共轭聚合物单分子的荧光轨迹和对应的发射偶极取向变化识别共轭聚合物单分子发光单元,发现延伸构象下的单分子呈现多发色团发光特性,而折叠构象下的单分子保持高效链间能量转移,呈现单个发色团发光特性.共轭聚合物单分子构象对能量转移效率的影响可用于研究基于共轭聚合物的光电器件和分子器件.     

Non-Abelian Geometric Manipulation of a Crystal of Molecular NanomagnetMn12

Based on the strong magnetic anisotropy along the symmetry of the crystal, we construct a U(2) non-Abelian gauge potential for the molecular nanomagnet Mn₁₂ by varying the external magnetic field adiabatically. Moreover, the non-Abelian geometric phase and the unitary matrix operation, which are the key steps to realize the universal holonomic quantum computing in the degenerate subspace, are also obtained by means of choosing an evolution path properly.     

Quantum Entanglement Dynamics of Two Atoms in Quantum Light Sources

Quantum entanglement dynamics of two Tavis-Cummings atoms interacting with the quantum light sources in a cavity is investigated. The results show the phenomenon that the concurrence disappears abruptly in a finite time, which depends on the initial atomic states and the properties of squeezed states. We find that there are two decoherence-free states in squeezed vacuum fields: one is the singlet state, and the other entangled state is the state
that combines both excited states and ground states with a relative phase being equal to the phase of the squeezed state.     

VB6与不同CopC作用的光谱研究

在室温, pH 7.4, 10mmol?L-1 Hepes缓冲溶液条件下, 通过紫外差光谱,荧光光谱法研究了apoCopC、CuN-CopC与Ag+的结合性质,进一步研究了apoCopC、 CuN-CopC、CopC-AgC 和CuN-CopC-AgC 与 Vitamin B6 作用的超分子行为. 结果表明：在 apoCopC与Ag+剂量比为1:1时,Ag+可以占据apoCopC蛋白C端的Cu+ 结合位点,结合常数为(1.68±0.33)×104mol?L-1. apoCopC结合不同的金属离子后,与Vitamin B6结合位点数明显减少.